
Photovoltaic (PV) cells, commonly called solar cells, are non-mechanical devices that can convert sunlight directly into electricity. This process, known as the photovoltaic effect, occurs when photons from sunlight strike the surface of the solar cell, which is typically made of semiconductor materials like silicon. The energy from the photons excites electrons in the semiconductor material, causing them to break free from their atomic bonds and creating a flow of electrons, which is an electrical current. This electricity can then be harnessed and used to power electrical devices. PV cells have a wide range of applications, from powering small devices like calculators to providing electricity for entire communities. They offer a clean, renewable, and sustainable source of energy with no harmful emissions.
| Characteristics | Values |
|---|---|
| Process | Photons from the sun's rays strike the surface of the solar cell, exciting electrons and creating an electrical current. |
| Cell Material | Semiconductor materials like silicon, the most common type, or other materials such as germanium and cadmium telluride. |
| Cell Type | Monocrystalline silicon, polycrystalline silicon, thin-film, or experimental types for specific applications. |
| Efficiency | Commercially available PV panels averaged less than 10% efficiency in the mid-1980s, increasing to around 15% by 2015, and now approaching 25%. Experimental cells have achieved nearly 50% efficiency. |
| Benefits | Clean, renewable energy with no harmful emissions, reduced dependence on fossil fuels, potential cost savings, and a more resilient energy grid. |
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What You'll Learn

Photons strike the solar cell
Photons from the sun's rays strike the surface of the solar cell, which is typically made of semiconductor materials like silicon. When photons carrying sufficient energy hit the PV cell, they are absorbed by the semiconductor material. This process is called photon absorption.
The photons must have enough energy to overcome the effective mass of the electron and the semiconductor material's band gap to free an electron. If the photons do not carry enough energy, the electrons will not break free from their electron-hole pairs. At other times, the photons may carry more energy than is required, and the excess energy is wasted.
When the semiconductor material absorbs enough sunlight, the photons energize electrons within the silicon atoms, causing them to break free from their atomic bonds. This process is called electron excitation. The freed electrons then move together around an external circuit, creating an electron flow or current.
The PV cell is designed with two layers of silicon—one positively charged (p-type) and one negatively charged (n-type). This creates an electric field that directs the flow of freed electrons, generating an electric current. This current, along with the voltage provided by the internal electric field, produces electrical power.
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Photons are absorbed by the semiconductor material
Photons are the tiny packets of energy that make up sunlight. When photons strike a photovoltaic (PV) cell, they will either reflect off the cell, pass through the cell, or be absorbed by the semiconductor material. Only the photons that are absorbed by the semiconductor material can be converted into electricity.
Semiconductors are non-metallic materials, such as silicon, germanium, and gallium arsenide, whose solar cell I-V characteristic lies somewhere between those of a conductor and an insulator. Silicon is by far the most common semiconductor material used in solar cells, representing approximately 95% of the modules sold today. It is the second most abundant material on Earth, after oxygen, and is used in most modern electronics.
When a photon strikes the semiconductor material, it excites an electron, causing it to break free from its covalent bond with the silicon atom. This process is called electron excitation. The energy of the photon is transferred to the electron, allowing it to flow through the material as an electrical current. This current can then be extracted through conductive metal contacts and used to power electrical devices.
The efficiency of a PV cell depends on the amount of electrical power coming out of the cell compared to the energy from the light shining on it. The bandgap of the semiconductor material also plays a role in efficiency, as it indicates what wavelengths of light the material can absorb and convert into electrical energy. If the bandgap matches the wavelengths of light shining on the PV cell, the cell can efficiently utilize all the available energy.
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Electrons are excited and freed
The photovoltaic effect is the process by which solar cells convert sunlight into electrical energy. This phenomenon occurs when photons from the sun's rays strike the surface of the solar cell, which is typically made of semiconductor materials like silicon.
When photons strike the surface of a photovoltaic (PV) cell, they may be reflected, pass through the cell, or be absorbed by the semiconductor material. Only the photons that are absorbed by the semiconductor material provide energy to generate electricity. Photons are particles of light that contain varying amounts of energy, corresponding to the different wavelengths of the solar spectrum.
When a photon with sufficient energy strikes the semiconductor material, it excites an electron, freeing it from its atomic bond. This process is called electron excitation. The absorbed photons energize electrons within the silicon atoms, causing them to break free from their atomic bonds. This freed electron, along with the hole (absence of an electron) it leaves behind, creates an electron-hole pair.
The energy of the photons excites electrons into a state called "electron-hole pairs". When these are formed in the vicinity of the electric field at the junction of the p-type and n-type layers, the electric field pulls the pair apart, creating a "charge-separated" state. This excitation of electrons is a crucial step in the process of converting sunlight into electricity through the photovoltaic effect.
The semiconductor material used in PV cells is typically silicon, which has a unique arrangement of electrons. Silicon has four out of a possible eight electrons in its outermost shell, allowing it to form perfect covalent bonds with four other silicon atoms, creating a lattice structure. This lattice structure facilitates the efficient conversion of light into electricity.
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An electron flow is created
Photovoltaic (PV) cells, commonly known as solar cells, are made of semiconductor materials that can absorb sunlight and generate an electrical current through the photovoltaic effect. This effect occurs when photons from the sun's rays strike the surface of the solar cell, exciting an electron and freeing it from its atomic bond. This process creates an electron-hole pair.
The PV cell is designed with two layers of silicon, one positively charged (p-type) and one negatively charged (n-type). This creates an electric field that directs the flow of the freed electrons, generating an electric current. The semiconductor material is designed with a built-in electric field that separates the electron-hole pairs, forcing the electrons to flow in one direction and the holes in the opposite direction. This flow of electrons constitutes an electrical current, which can be harnessed and utilised as electricity.
The photovoltaic effect is a highly efficient process with no moving parts, making solar cells a reliable and low-maintenance source of electricity. The first silicon photovoltaic cell was demonstrated in 1954, and since then, the technology has been refined to improve efficiency and performance. Today, solar panels are becoming an increasingly popular option for domestic electricity production, providing a clean, renewable, and sustainable source of energy.
The efficiency of PV cells in converting sunlight into electricity depends on various factors, including the type of semiconductor material, the design and manufacturing processes, and the presence of any defects or impurities in the cell structure. Experimental PV cells have achieved nearly 50% efficiency, while commercially available PV panels have efficiencies approaching 25%. Proper maintenance and cleaning of solar panels can also help ensure optimal performance and efficiency over time.
The movement of electrons and holes generates electricity, and as long as there is light striking the cell, there will be a flow of electrons. This electron flow, along with the voltage provided by the internal electric field, produces electrical power. The electricity generated by the PV cells can be used to power devices directly or stored in batteries for later use, contributing to a more resilient and diversified energy grid.
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Electricity is generated
Solar panels, also known as photovoltaic (PV) modules, are designed to convert sunlight into electrical energy. PV cells are made of semiconductor materials, most commonly silicon, which can absorb sunlight and generate an electrical current through the photovoltaic effect. This effect occurs when photons from the sun's rays strike the surface of the PV cell, exciting electrons and freeing them from their atomic bonds. This movement of electrons creates an electrical current, which can be harnessed and utilized as electricity.
The process of converting sunlight into electricity through PV cells involves several key steps. Firstly, sunlight, composed of photons or packets of energy, strikes the surface of the PV cell. The photons are then absorbed by the semiconductor material, typically silicon, through a process known as photon absorption. Not all photons are absorbed, some may reflect off the cell or pass through it. The absorbed photons carry varying amounts of energy, and when they have sufficient energy, they excite and dislodge electrons from the material's atoms, a process known as electron excitation.
The PV cell is designed with two layers of silicon, one positively charged (p-type) and one negatively charged (n-type), creating an electric field. This electric field directs the flow of the freed electrons, ensuring they move in a specific direction. The movement of electrons towards the front surface of the PV cell creates an imbalance of electrical charge, resulting in a voltage potential. This voltage potential is similar to the negative and positive terminals of a battery.
The freed electrons naturally migrate to the surface of the cell due to special treatments applied during manufacturing, and they flow as a current within an external circuit when electrical conductors on the PV cell absorb them. This electron flow, along with the voltage potential, generates electrical power. The electricity produced can then be utilized to power devices directly or stored in batteries for later use.
PV cells have become an increasingly popular option for electricity generation due to their clean, renewable, and sustainable nature. They produce no harmful emissions during operation and offer reduced dependence on fossil fuels, contributing to a lower carbon footprint. With advancements in technology and decreasing costs, PV cells are playing a significant role in the transition to clean energy sources.
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Frequently asked questions
Photovoltaic cells, or solar cells, are non-mechanical devices that convert sunlight directly into electricity. They are made of semiconductor materials such as silicon, the second most abundant material in the world after oxygen.
Photovoltaic cells convert sunlight into electricity through a process called the photovoltaic effect. When sunlight strikes a photovoltaic cell, it is composed of tiny packets of energy called photons. These photons are absorbed by the semiconductor material, which causes electrons to be dislodged from the material's atoms, creating an electric current.
Photovoltaic cells provide a clean, renewable, and sustainable source of electricity with no harmful emissions during operation. They reduce dependence on fossil fuels and lower carbon footprints. They also have the potential to significantly reduce electricity costs over time.

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